Well, I think a lot of how the light will dissipate will depend on where you place the leds, as well as the surface texture of the the part you are lighting. If you place the leds on the edge of the piece, and the surface texture is smooth the leds will light the edge of the acrylic and not much else. It you rough up the surface, the light will scatter off the surface and light up the part better.
A lot will also depend on the optical clarity of the resin you use and how well you get the air bubbles out.
Oh, and I don't think you would have to worry about messing with the circuity if it is cast in the resin. Plastics are typically poor conductors of electricity.



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