im not going to explain in great detail but i will explain the basics.
fiberglass is a type of fabric made from woven glass fibers and plastic reinforced by glass fibers. it is the material that defines a shape and makes it hard.
body filler or bondo is a polyester material used to smooth out bodywork or used to repair dents or dings in metal.
you first lay out fiberglass to make a general shape of what you want. fiberglass makes it sturdy and hard. then you put bondo over the fiberglass to smooth everything out.
it just depends on what you are doing (project wise) but i prefer to work with body filler more because its the layer that makes everything looks smooth and perfect and is pretty easy to use, after you get used to it. fiberglass is sorta hard to work with since its stringy and sticky.
hope that helps



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