Then if you have a charge light, search for the UIBI - it's the best battery isolator for most applications with none of the drawbacks of voltage-sensing or "smart" (LOL) isolators.
The UIBI is merely a relay controlled by the charge light circuit so it does exactly what you want.
Note that some alternator charge-light circuits may have difficulty energising
relays (and may be damaged), and many alternators - actually their regulators - may likewise have difficulties providing the 1A or 2A etc required for large relays (isolators) - eg, 200A and above, In the latter case, a normal 30A relay or smaller can be used as a buffer (the charge lamp energises the small relay which in turn energises the main isolator, and any number of isolators).
Of course the isolator will be connected between the batteries and have a fuse or breaker at EACH end close to each battery (unless, perhaps, they are next to each other).
There should be some (old?) indicative diagrams with my
mp3car UIBI posts.
If the UIBI or voltage sensing isolator is used, the IGN circuit is irrelevant.
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