that's a common issue when dealing with externally powered usb hubs. You're getting a voltage spike from the car's
power, that in turn, locks up the computer.
However, to overcome this issue it is best to use hubs that use two connections to your computer in the form of an USB "Y" cable- one for the usb signal, the other for the 5v input. But, you must also try not exceed your motherboards USB output amperage.
It also sounds like you're powering the hub through the cars power window fused circuit.
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