Hi!
About voltages now :
1. +12V - uses by HD(cd, dvd, etc ide-satadevices), intel processors psu, motherboard
2.+5v - uses by HD(and etc ide-sata devices) , amd processor psu, motherboard, some models RAM psu.
3. +3.3 V uses by sata, pci, agp devices AND IN MOST MODELS OF MOTHERBOARDS-RAM PSU!
4.-12V - uses by COM port, Infrared transmitter port, and usart
5. !!!!! -5v - DON'T used now ! typicaly in old systems was used for ISA card devices