I think you will want to go with 0 for 80 amps. The reason for this is because how large of a stretch it is. If you only needed 10 feet of wire, 4 would do it, but I figured it at 18, and came up with 0 gauge. And dont run it under the car... do it the right way (under carpet).
http://knukonceptz.com is a good place to get wire
Welding stores apparently sell the wire cheaper, but I really dont think its as nice as the Knu stuff (flexibility is really nice when installing, and I dont know how well the welding cable would flex)
Matt