A VGA adapter "Y" cable will work, but you'll get the SAME image on both monitors. If that's what you're going for, then it's a pretty simple setup.
However, if you want different images on the two different monitors (which is the setup bbalazs was describing), you'll definitely need a second video card. For your situation, you could use a USB video adapter like the following:
http://www.usbgear.com/USB-Video-Card.html
Mind you, I just did a quick Google search for "USB video cards", so you'll probably want to shop around more.
Good luck.
FYI... I'm doing a hybrid of both... two video cards, LCD touch screen up front for primary control, two video screens in the back (both connected with a "Y" to the secondary video card) so the two back screens show the same image. Not sure what front-ends are going to support that yet, or if I'll have to roll something on my own.
David