In terms of performance? Mine's not actually mounted in my car yet due to lack of time and lack of 12V -> 7.5V DC DC converter.
Comparing it to some LCDs i've seen at Strathfield here, the image quality is much better if you use a proper composite sync from an ATi video card.
If you look at the display straight on perpendicular to the image, it looks great. If you deviate and rotate the panel along the horizontal axis, the image disappears quite quickly, so you'll need to arrange yout mount so it's perpendicular to the person who wants to look at it.
Bear in mind that your GPS software has to support nonstandard video resolutions in order for it to work on the PSOne LCD, as it has to run at 720x576 instead of 640x480 or 800x600. Also check how your GPS software works, does it draw itself with Windows GDI or something else? (I'd imagine most are GDI though..).
And also if you use the XOR hack to combine HSync and VSync, the video quality isn't the best and the display will look like every second line is missing.
Running Media Engine should be fine, as it's DDraw, and i managed to get Azubeach running on mine.
The mod i wrote up only works for Sony PSOne LCDs. There are other people working on non-Sony LCDs, you should be able to find these by searching for them on the forums. I wouldn't take the gamble and try a non-Sony one, as the RGB signal voltages they want might be different. Some of the non-Sony ones also don't appear to support the RGB out signal at all and just run off the composite out.
Oh and my website's offline for the moment because my upstream provider's radio link's died over the weekend >_<