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I really doubt it has anything to do with com3 and com4, but you may be onto something with the modem. You should try disconnecting it. Since that hub is underpowered, it could still be causing the problem. See, all the devices including the wi-fi, modem, hub, PC, GPS, everything has capacitors that discharge over several minutes when the PC turns off, so waiting say an hour causes a larger surge than waiting several seconds. Too much can drop the voltage too low and mess things up when they are trying to initialize. That could very well be happening. You could test by unplugging the modem or wi-fi, or both. If that does fix it, find out how that hub was powered before.
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