I am in the same boat as everyone else in here but I havent received my unit yet and I have not bought a PSU yet either. The pinouts though are described in this thread:
http://www.mp3car.com/vbulletin/showthread.php?t=21812 at the VERY BOTTOM there is 2 .pdf files the bottom one has the pin out readings and also shows how to hook it up to a m1-atx although with the newer p3 SFFs you are prolly going to need a m2-atx PSU. I have not started on my carPC other than software so I have not confirmed this yet.
it is really nice though that as soon as I start posting questions about my PSU issues that 3 other post come up about the same thing.